Theoretical Study of Exo-Endo Interconversion of [(R)Ca1ixTMS2]Sn

author

  • Avat (Arman) Taherpour -
Abstract:

The 1, 3-bis(trimethyl silyl)ether of p-tert-butyl calix[4]arene, Rt-Bu)Ca1ixTMS21112, has beensynthesized and used as a dianionic ligand for "Sn". The complex of [(t-Bu)Ca1ixTMS2]Snexhibits exo and endo isomerism. The structural properties of [(Rp)Ca1ixTMS2]Sn, (Rpara= H,CH3, t-Bu) and the inter conversion of exoendo isomers were investigated by using of SCF-MOPM3 method.

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volume 5  issue 1

pages  1- 8

publication date 2008-05-01

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